![]() ![]() (WHG) (Ĭombined internal and external transport resistances. Reaction and diffusion in porous catalysts (cont.). Effective diffusivity, internal and overall effectiveness factor, Thiele modulus, apparent reaction rates. Reaction and diffusion in porous catalysts. Applications of gas-liquid transport with reaction. (WHG) (Įxternal mass-transfer resistance: Gas-liquid reactions in multiphase systems. Non-porous packed beds and monoliths, immobilized cells. Inorganic and enzyme catalysts and their properties kinetics of heterogeneous catalytic reactions adsorption isotherms, derivation of rate laws Langmuir-Hinshelwood kinetics. Approach to steady state receptor trafficking. Gene expression and trafficking dynamics. Significance typical values and diffusion limit approach to equilibrium multivalency. Kinetics of non-covalent bimolecular interactions. Fed batch or semi-continuous fermentor operation. Experimental methods for the determination of kinetic parameters of chemical and enzymatic reactions determination of cell growth parameters statistical analysis and model discrimination. Derivation of energy balances for ideal reactors equilibrium conversion, adiabatic and nonadiabatic reactor operation. How choice of reactor affects selectivity vs. Reactor size comparisons for PFR and CSTR. (WHG) (īatch reactor: Equations, reactor sizing for constant volume and variable volume processes. (KDW) (Ĭoncentration that optimizes desired rate. (WHG) (Ĭontinuous stirred tank reactor (CSTR). Reaction mechanisms and rate laws: Reactive intermediates and steady state approximation in reaction mechanisms. Cell growth kinetics substrate uptake and product formation in microbial growth enzyme kinetics, Michaelis-Menten rate form. The reaction rate and reaction mechanisms: Definition in terms of reacting compounds and reaction extent rate laws, Arrhenius equation, elementary, reversible, non-elementary, catalytic reactions. Single reactions and reaction networks, bioreaction pathways. Reaction stoichiometry, lumped stoichiometries in complex systems such as bioconversions and cell growth (yields) extent of reaction, independence of reactions, measures of concentration. Preliminaries and remembrance of things past. They are preliminary and may contain errors. These lecture notes were prepared by Tiffany Iaconis, Frederick Jao, and Vicky Loewer for MIT OpenCourseWare. Arrow_back browse course material library_books ![]()
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